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Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

[ Vol. 1 , Issue. 2 ]

Author(s):

Ram Naresh Yadav, Ashwini Bobbala, Sunena Chandra and Bimal K. Banik   Pages 94 - 97 ( 4 )

Abstract:


Bismuth nitrate-catalyzed microwave-assisted one-pot three components Aza-Diels-Alder reaction has been investigated. This method has been used for an efficient synthesis of 2-azabicyclo[2,2,2] cyclooctanones.

Keywords:

Alkaloids, aza-Diels-Alder, azabicycle, bismuth nitrate, cycloadducts, diastereoselectivity, dienophile, endo/exo, heterocycles, in situ, keto-enol tautomerization, Lewis acid, microwave chemistry, natural product, one-pot chemistry.

Affiliation:

Department of Chemistry, The University of Texas Pan American, 1201 West University Drive, Edinburg, Texas 78539, USA.

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